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In this chapter, I covered the techniques that you need to know to work with xrefs. You read about: Attaching and overlaying xrefs Opening an xref in its own window Editing xrefs and blocks from within the drawing in which they appear Clipping xrefs so that only the portion you need to see is displayed Setting spatial and layer indexes to speed up the display of large xrefs Deleting, unloading, and reloading xrefs Binding an xref to make it part of your drawing In the next chapter, I cover database connectivity, which enables you to access outside databases.

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These alternative sources of risk management guidance do not conflict with one another and there is value in each of them. Some features of each one that might affect how they are used are set out below.

All associated control channels have the same direction (bidirectional or unidirectional) as the channels with which they are associated.

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HYDROGEN BONDS AND PROTON ABSTRACTION REACTIONS Hydrogen atoms form the exposed outer surface of the majority of organic molecules A reagent su ering a random collision with a substrate is most likely to encounter a bonded hydrogen atom The interaction between a substance B and a compound in the vicinity of a hydrogen atom, bonded to an element which is more electronegative than it is (which includes C), is shown in Figure 101 The important interaction is a two-electron, two-orbital interaction between the HOMO of B and the antibonding s orbital of the bond to H (s ).

Following are some key points discussed in this chapter:

If the s orbital involves H and C, it probably will not be the LUMO, and if B is not extraordinarily basic, that is, does not have a very high energy, localized HOMO, then little consequences will ensue from the interaction other than a weak van der Waals [72] interaction which is always present If the s orbital is the LUMO, the interaction, which involves charge transfer may be quite strong resulting either in a complex stabilized by a hydrogen bond or rupture of the s bond with concomitant transfer of the proton to B, a Lowry Bronsted acid base reaction Bonds to hydrogen from O and F, and probably N, are highly polarized and there will be a substantial electrostatic component to the interaction if B is even partially negatively charged In Figure 101, the HOMOs of the bases B: and A: are depicted as generic s orbitals.

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In fact, these could be nonbonded p or sp n hybrid orbitals, or also p orbitals as in alkenes, enolates, or enamines, or strained s bonding MOs as in cyclopropanes Hydrogen Bonds Hydrogen-bonding interactions are considerably weaker than ionic interactions and covalent bonds but have a profound e ect on many chemical and physical properties [221] and determine the shapes of large molecules such as proteins and nucleic acids Protein secondary structure is determined by H bonding between the carbonyl oxygen of one amide unit and the N H bond of another The two strands of the double helix of.

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